catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)dysprosium(III)] [molybdenum(VI)-di-μ-sulfido-silver(I)-di-μ-sulfido]]
نویسنده
چکیده
Hexamethyl-phospho-ramide (hmp), tetra-thio-molybdate, silver sulfide and dysprosium nitrate were self-assembled to form an anionic [AgMoS(4)](n) (n-) chain in the title complex, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two nitrate and four hmp ligands, resulting in a distorted square-anti-prismatic environment. Together with the two nitrate ligands, the cation is monovalent, which leads to the anionic chain having an [AgMoS(4)] repeat unit. The polymeric anionic chain, with Mo-Ag-Mo and Ag-Mo-Ag angles of 161.911 (13) and 154.014 (13)°, respectively, presents a distorted linear configuration. The title complex is isostructural with the W analogue.
منابع مشابه
catena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)samarium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
The Sm atom in the cation of the title salt, {[Sm(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgS(4)W]}(n), is coordinated by eight O atoms derived from two chelating nitrate anions, and four hexamethylphos-phoramide ligand, defining a distorted square-antiprismatic geometry. The anions self-assemble into polymeric chains via W-S-Ag bridges having a [AgS(4)W] repeat unit; the W-Ag-W and Ag-W-Ag angles are 1...
متن کاملcatena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)dysprosium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
Hexa-methyl-phospho-ramide (hmp), tetra-thio-tungstate, silver sulfide and dysprosium nitrate were self-assembled, forming an anionic [AgWS(4)](n) (n) (-) chain in the title compound, {[Dy(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The central Dy atom in the cation is coordinated by eight O atoms from two didentate nitrate and four hmp ligands, giving rise to a distorted square anti-prismatic...
متن کاملcatena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)yttrium(III)] [silver(I)-di-μ-sulfido-molybdenum(VI)-di-μ-sulfido]]
In the cation of the title compound, {[Y(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgMoS(4)]}(n), the Y atom is coordinated by eight O atoms from two chelating nitrate groups and four hexa-methyl-phospho-ramide (hmp) ligands, which gives rise to a distorted square-anti-prismatic environment. Together with the two nitrate ligands, the overall charge for the complex cation is +1, which leads to the anionic ...
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In the title compound, {[Lu(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n), hexa-methyl-phospho-ramide (hmp), tetra-thio-tungstate, silver iodide and lutetium nitrate were self-assembled, forming an anionic {[AgWS(4)](-)}(n) chain extending parallel to [001]. The Lu(III) atom in the cation is coordinated by eight O atoms from two nitrate groups and four hmp ligands in a distorted square-anti-prism...
متن کاملcatena-Poly[[tetrakis(hexamethylphosphoramide-κO)bis(nitrato-κ2 O,O′)cerium(III)] [silver(I)-di-μ-sulfido-tungstate(VI)-di-μ-sulfido]]
Hexa-methyl-phospho-ramide (hmp), tetra-thio-tungstate, silver sulfide and cerium nitrate were self-assembled to form a one-dimensional anionic [Ag(4)W(4)S(16)](n) (4n-) chain in the title compound, {[Ce(NO(3))(2)(C(6)H(18)N(3)OP)(4)][AgWS(4)]}(n). The asymmetric unit contains four crystallographically independent [Ce(hmp)(4)(NO(3))(2)](+) cations, which leads to a one-dimensional polymeric ani...
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